UiO-66

Oct. 4, 2022, 1:43 p.m.

References

A flexible two-dimensional layered metal-organic framework functionalized with (trifluoromethyl)trifluoroborate: synthesis, crystal structure, and adsorption/separation properties. A lithium-modified zirconium-based metal organic framework (UiO-66) for efficient CO2 adsorption. A systematic evaluation of UiO-66 metal organic framework for CO2/N2 separation. Enhancing Van der Waals Interactions of Functionalized UiO-66 with Non-polar Adsorbates: The Unique Effect of para Hydroxyl Groups. Experimental Study of CO2, CH4, and Water Vapor Adsorption on a Dimethyl-Functionalized UiO-66 Framework. Fine-tuning the pore structure of metal-organic frameworks by linker substitution for enhanced hydrogen storage and gas separation. Polydopamine-Modified Metal-Organic Framework Membrane with Enhanced Selectivity for Carbon Capture. Structural modulation of UiO-66-NH2 metal-organic framework via interligands cross-linking: Cooperative effects of pore diameter and amide group on selective CO2 separation. Tuning the Adsorption Properties of UiO-66 via Ligand Functionalization.

Data points

#	Adsorbent	Gas	q / mol kg⁻¹	S / mol mol⁻¹	-ΔH / kJ mol⁻¹
430	UiO-66	Argon/Oxygen	0.36	1.0	None
634	UiO-66	Carbon dioxide/Argon	3.57	10.0	None
934	UiO-66	Carbon dioxide/Methane	1.85	8.0	31.0
937	UiO-66	Carbon dioxide/Methane	1.28	3.7	None
1003	UiO-66	Carbon dioxide/Methane	2.4	6.75	None
1209	UiO-66	Carbon dioxide/Methane	2.3	6.05	None
1621	UiO-66	Carbon dioxide/Methane	1.5	3.4	None
1655	UiO-66	Carbon dioxide/Methane	1.75	10.1	23.7
2102	UiO-66	Carbon dioxide/Hydrogen	1.28	70.7	None
2258	UiO-66	Carbon dioxide/Nitrogen	3.57	10.0	None
2510	UiO-66	Carbon dioxide/Nitrogen	1.28	8.6	None
2563	UiO-66	Carbon dioxide/Nitrogen	2.4	10.8	None
2662	UiO-66	Carbon dioxide/Nitrogen	2.37	26.5	None
2697	UiO-66	Carbon dioxide/Nitrogen	1.3	5.65	17.5
3432	UiO-66	Carbon dioxide/Nitrogen	1.75	37.5	23.7
3864	UiO-66	Nitrogen/Argon	0.36	1.0	None
3956	UiO-66	Nitrogen/Oxygen	0.36	1.0	None