Fine-tuning the pore structure of metal-organic frameworks by linker substitution for enhanced hydrogen storage and gas separation.
DOI: 10.1039/d1ce00087jJan. 1, 2021
Adsorbents
Data points
| # | Adsorbent | Gas | q / mol kg⁻¹ | S / mol mol⁻¹ | -ΔH / kJ mol⁻¹ |
|---|---|---|---|---|---|
| 937 | UiO-66 | Carbon dioxide/Methane | 1.28 | 3.7 | None |
| 938 | UiO-66-(OH)2 | Carbon dioxide/Methane | 1.62 | 6.8 | None |
| 939 | UiO-66-(OCH3)2 | Carbon dioxide/Methane | 1.21 | 6.3 | None |
| 940 | UiO-66- (OCH2CH3)2 | Carbon dioxide/Methane | 0.83 | 6.8 | None |
| 2102 | UiO-66 | Carbon dioxide/Hydrogen | 1.28 | 70.7 | None |
| 2103 | UiO-66-(OH)2 | Carbon dioxide/Hydrogen | 1.62 | 89.1 | None |
| 2104 | UiO-66-(OCH3)2 | Carbon dioxide/Hydrogen | 1.21 | 16.8 | None |
| 2105 | UiO-66- (OCH2CH3)2 | Carbon dioxide/Hydrogen | 0.83 | 5.1 | None |
| 2510 | UiO-66 | Carbon dioxide/Nitrogen | 1.28 | 8.6 | None |
| 2511 | UiO-66-(OH)2 | Carbon dioxide/Nitrogen | 1.62 | 24.5 | None |
| 2512 | UiO-66-(OCH3)2 | Carbon dioxide/Nitrogen | 1.21 | 19.5 | None |
| 2513 | UiO-66- (OCH2CH3)2 | Carbon dioxide/Nitrogen | 0.83 | 20.5 | None |