Tuning the Adsorption Properties of UiO-66 via Ligand Functionalization.
DOI: 10.1021/la3035352Jan. 1, 2012
Adsorbents
-
UiO-66
UiO-66
UiO-66-1, 4-Naphthyl
UiO-66-2,5-(OMe)2
UiO-66-NH2
UiO-66-NO2
UiO-66−1,4-Naphyl
UiO-66−2,5-(OMe)2
UiO-66−NH2
UiO-66−NO2
Data points
| # | Adsorbent | Gas | q / mol kg⁻¹ | S / mol mol⁻¹ | -ΔH / kJ mol⁻¹ |
|---|---|---|---|---|---|
| 1655 | UiO-66 | Carbon dioxide/Methane | 1.75 | 10.1 | 23.7 |
| 1656 | UiO-66−NH2 | Carbon dioxide/Methane | 3.08 | 17.0 | 26.5 |
| 1657 | UiO-66−NO2 | Carbon dioxide/Methane | 1.86 | 12.3 | 26.9 |
| 1658 | UiO-66−1,4-Naphyl | Carbon dioxide/Methane | 1.54 | 6.5 | 27.1 |
| 1659 | UiO-66−2,5-(OMe)2 | Carbon dioxide/Methane | 2.65 | 18.0 | 27.3 |
| 3432 | UiO-66 | Carbon dioxide/Nitrogen | 1.75 | 37.5 | 23.7 |
| 3433 | UiO-66−NH2 | Carbon dioxide/Nitrogen | 3.08 | 66.5 | 26.5 |
| 3434 | UiO-66−NO2 | Carbon dioxide/Nitrogen | 1.86 | 51.4 | 26.9 |
| 3435 | UiO-66−1,4-Naphyl | Carbon dioxide/Nitrogen | 1.54 | 30.0 | 27.1 |
| 3436 | UiO-66−2,5-(OMe)2 | Carbon dioxide/Nitrogen | 2.65 | 62.2 | 27.3 |
| 4982 | UiO-66 | Methane/Nitrogen | 0.5 | 3.7 | 18.5 |
| 4983 | UiO-66-NH2 | Methane/Nitrogen | 0.67 | 2.98 | 22.0 |
| 4984 | UiO-66-1, 4-Naphthyl | Methane/Nitrogen | 0.45 | 3.75 | 21.0 |
| 4985 | UiO-66-NO2 | Methane/Nitrogen | 0.67 | 4.47 | 22.5 |
| 4986 | UiO-66-2,5-(OMe)2 | Methane/Nitrogen | 0.6 | 3.0 | 22.0 |