Enhancing Van der Waals Interactions of Functionalized UiO-66 with Non-polar Adsorbates: The Unique Effect of para Hydroxyl Groups.
DOI: 10.1002/chem.201704779Jan. 1, 2018
Adsorbents
Data points
| # | Adsorbent | Gas | q / mol kg⁻¹ | S / mol mol⁻¹ | -ΔH / kJ mol⁻¹ |
|---|---|---|---|---|---|
| 1206 | UiO-66-(OH)2 | Carbon dioxide/Methane | 6.0 | 7.14 | None |
| 1207 | UiO-66-OH | Carbon dioxide/Methane | 3.5 | 6.25 | None |
| 1208 | UiO-66-NH2 | Carbon dioxide/Methane | 3.1 | 6.2 | None |
| 1209 | UiO-66 | Carbon dioxide/Methane | 2.3 | 6.05 | None |
| 1210 | UiO-66-OCF3 | Carbon dioxide/Methane | 2.2 | 4.58 | None |
| 1211 | UiO-66-NO2 | Carbon dioxide/Methane | 2.3 | 4.79 | None |
| 4802 | UiO-66-(OH)2 | Methane/Nitrogen | 0.84 | 6.36 | None |
| 4803 | UiO-66-OH | Methane/Nitrogen | 0.56 | 5.83 | None |
| 4804 | UiO-66-NH2 | Methane/Nitrogen | 0.5 | 5.95 | None |
| 4805 | UiO-66 | Methane/Nitrogen | 0.06 | 1.68 | None |
| 4806 | UiO-66-OCF3 | Methane/Nitrogen | 0.47 | 8.39 | None |
| 4807 | UiO-66-NO2 | Methane/Nitrogen | 0.48 | 7.06 | None |