Enhancing Gas Adsorption and Separation Capacity through Ligand Functionalization of Microporous Metal-Organic Framework Structures.

DOI: 10.1002/chem.201002818

Jan. 1, 2011

Adsorbents

Data points

# Adsorbent Gas q / mol kg⁻¹ S / mol mol⁻¹ -ΔH / kJ mol⁻¹
1841 [Zn(BDC)(TED)0.5]1’ Carbon dioxide/Methane 2.01 4.0 20.2
1842 [Zn(BDC-OH)(TED)0.5] 2’ Carbon dioxide/Methane 2.94 7.0 24.2
3579 [Zn(BDC)(TED)0.5]1’ Carbon dioxide/Nitrogen 2.01 15.0 20.2
3580 [Zn(BDC-OH)(TED)0.5] 2’ Carbon dioxide/Nitrogen 2.94 23.0 24.2
4026 [Zn(BDC)(TED)0.5]1’ Nitrogen/Oxygen 0.13 1.07 None
4027 [Zn(BDC-OH)(TED)0.5] 2’ Nitrogen/Oxygen 0.13 1.53 None
5030 [Zn(BDC)(TED)0.5] 1' Methane/Nitrogen 0.45 3.33 None
5031 [Zn(BDC-OH)(TED)0.5] 2’ Methane/Nitrogen 0.45 3.33 None