Reversible and Selective O2 Chemisorption in a Porous Metal-Organic Host Material.

DOI: 10.1021/ja202228v

Jan. 1, 2011

Adsorbents

Data points

# Adsorbent Gas q / mol kg⁻¹ S / mol mol⁻¹ -ΔH / kJ mol⁻¹
3568 [{CoII 2(bpbp)}2bdc](PF6)4 Carbon dioxide/Nitrogen 0.24 20.0 None
3569 [{CoII 2(bpbp)}2bdc](PF6)4 ·2O2 Carbon dioxide/Nitrogen 0.87 34.55 None
4165 [{CoII 2(bpbp)}2bdc](PF6)4 Oxygen/Argon 0.92 78.4 55.0
4166 [{CoII 2(bpbp)}2bdc](PF6)4 ·2O2 Oxygen/Argon 0.07 2.73 55.0
4256 [{CoII 2(bpbp)}2bdc](PF6)4 Oxygen/Nitrogen 0.92 78.4 55.0
4257 [{CoII 2(bpbp)}2bdc](PF6)4 ·2O2 Oxygen/Nitrogen 0.07 2.73 55.0