A combined experimental and quantum chemical study of CO2 adsorption in the metal-organic framework CPO-27 with different metals.
DOI: 10.1039/c3sc51319jJan. 1, 2013
Adsorbents
Data points
| # | Adsorbent | Gas | q / mol kg⁻¹ | S / mol mol⁻¹ | -ΔH / kJ mol⁻¹ |
|---|---|---|---|---|---|
| 1600 | CPO-27-Mg | Carbon dioxide/Methane | 9.0 | 130.0 | 42.0 |
| 1601 | CPO-27-Ni | Carbon dioxide/Methane | 6.8 | 45.0 | 38.0 |
| 1602 | CPO-27-Co | Carbon dioxide/Methane | 6.9 | 23.0 | 34.0 |
| 1603 | CPO-27-Mn | Carbon dioxide/Methane | 6.6 | 21.0 | 32.0 |
| 3349 | CPO-27-Ni | Carbon dioxide/Nitrogen | 6.8 | 85.0 | 38.0 |
| 3350 | CPO-27-Co | Carbon dioxide/Nitrogen | 6.9 | 52.0 | 34.0 |
| 3351 | CPO-27-Mn | Carbon dioxide/Nitrogen | 6.6 | 61.0 | 32.0 |