Adsorption and molecular simulation of CO2 and CH4 in two-dimensional metal-organic frameworks with the same layered substrate.

DOI: 10.1039/c3ce40838h

Jan. 1, 2013

Adsorbents

Data points

# Adsorbent Gas q / mol kg⁻¹ S / mol mol⁻¹ -ΔH / kJ mol⁻¹
1586 [Cu(1,3-BDC)(H2O)]·2H2O Carbon dioxide/Methane 0.67 20.14 40.12
1587 [Cu(1,3-BDC)(PY)2] Carbon dioxide/Methane 0.45 2.11 36.65
3338 [Cu(1,3-BDC)(H2O)]·2H2O Carbon dioxide/Nitrogen 0.67 414.7 40.12
3339 [Cu(1,3-BDC)(PY)2] Carbon dioxide/Nitrogen 0.45 9.4 36.65
4952 [Cu(1,3-BDC)(H2O)]·2H2O Methane/Nitrogen 0.04 1.0 20.0
4953 [Cu(1,3-BDC)(PY)2] Methane/Nitrogen 0.13 3.0 40.0