Adsorption and molecular simulation of CO2 and CH4 in two-dimensional metal-organic frameworks with the same layered substrate.
DOI: 10.1039/c3ce40838hJan. 1, 2013
Adsorbents
Data points
# | Adsorbent | Gas | q / mol kg⁻¹ | S / mol mol⁻¹ | -ΔH / kJ mol⁻¹ |
---|---|---|---|---|---|
1586 | [Cu(1,3-BDC)(H2O)]·2H2O | Carbon dioxide/Methane | 0.67 | 20.14 | 40.12 |
1587 | [Cu(1,3-BDC)(PY)2] | Carbon dioxide/Methane | 0.45 | 2.11 | 36.65 |
3338 | [Cu(1,3-BDC)(H2O)]·2H2O | Carbon dioxide/Nitrogen | 0.67 | 414.7 | 40.12 |
3339 | [Cu(1,3-BDC)(PY)2] | Carbon dioxide/Nitrogen | 0.45 | 9.4 | 36.65 |
4952 | [Cu(1,3-BDC)(H2O)]·2H2O | Methane/Nitrogen | 0.04 | 1.0 | 20.0 |
4953 | [Cu(1,3-BDC)(PY)2] | Methane/Nitrogen | 0.13 | 3.0 | 40.0 |