Effect of Pillar Modules and Their Stoichiometry in 3D Porous Frameworks of Zn(II) with [Fe(CN)6]3-: High CO2/N2 and CO2/CH4 Selectivity.
DOI: 10.1021/ic401657dJan. 1, 2013
Adsorbents
Data points
| # | Adsorbent | Gas | q / mol kg⁻¹ | S / mol mol⁻¹ | -ΔH / kJ mol⁻¹ |
|---|---|---|---|---|---|
| 1581 | {[Zn3(bipy)3- (H2O)2][Fe(CN)6]2·2(bipy)·3H2O}n | Carbon dioxide/Methane | 1.29 | 18.0 | 23.0 |
| 1582 | {[Zn3(azpy)2(H2O)2][Fe-(CN)6]2·4H2O}n | Carbon dioxide/Methane | 1.29 | 13.0 | 31.5 |
| 3331 | {[Zn3(bipy)3- (H2O)2][Fe(CN)6]2·2(bipy)·3H2O}n | Carbon dioxide/Nitrogen | 1.29 | 16.0 | 23.0 |
| 3332 | {[Zn3(azpy)2(H2O)2][Fe-(CN)6]2·4H2O}n | Carbon dioxide/Nitrogen | 1.29 | 62.0 | 31.5 |
| 4948 | {[Zn3(bipy)3- (H2O)2][Fe(CN)6]2·2(bipy)·3H2O}n | Methane/Nitrogen | 0.22 | 1.54 | None |
| 4949 | {[Zn3(azpy)2(H2O)2][Fe-(CN)6]2·4H2O}n | Methane/Nitrogen | 0.22 | 1.25 | None |