Comparison of conventional and HF-free-synthesized MIL-101 for CO2 adsorption separation and their water stabilities.

DOI: 10.1021/ef402212t

Jan. 1, 2013

Adsorbents

Data points

# Adsorbent Gas q / mol kg⁻¹ S / mol mol⁻¹ -ΔH / kJ mol⁻¹
629 MIL-101 Methane/Nitrogen 0.4 1.6 None
630 HF-free-synthesized MIL-101 Methane/Nitrogen 0.5 3.33 None
2031 MIL-101 Carbon dioxide/Methane 2.5 6.0 34.0
2032 HF-free-synthesized MIL-101 Carbon dioxide/Methane 2.0 5.0 31.0
3757 MIL-101 Carbon dioxide/Nitrogen 2.5 8.5 34.0
3758 HF-free-synthesized MIL-101 Carbon dioxide/Nitrogen 2.0 10.3 31.0
5077 MIL-101 Methane/Nitrogen 0.4 1.33 None
5078 HF-free-synthesized MIL-101 Methane/Nitrogen 0.5 3.33 None