The first example of commensurate adsorption of atomic gas in a MOF and effective separation of xenon from other noble gases.

DOI: 10.1039/C3SC52348A

Jan. 1, 2014

Adsorbents

Data points

# Adsorbent Gas q / mol kg⁻¹ S / mol mol⁻¹ -ΔH / kJ mol⁻¹
3837 Co3(HCOO)6 Krypton/Argon 0.78 5.57 21.7
4294 Co3(HCOO)6 Xenon/Argon 2.0 14.29 28.0
4341 Co3(HCOO)6 Xenon/Krypton 2.0 12.0 28.0