A 3D Porous Metal Organic Framework Based on Infinite 1D Nickel(II) Chains with Rutile Topology Displaying Open Metal Sites.

DOI: 10.1002/zaac.201400136

Jan. 1, 2014

Adsorbents

guest-free [Ni3(μ3-OH)2(TBAPy)(H2O)4]· (DMF)x(dioxane)x solvent-free [Ni3(μ3-OH)2(TBAPy)(H2O)4]· (DMF)x(dioxane)x

Data points

#	Adsorbent	Gas	q / mol kg⁻¹	S / mol mol⁻¹	-ΔH / kJ mol⁻¹
1547	guest-free [Ni3(μ3-OH)2(TBAPy)(H2O)4]· (DMF)x(dioxane)x	Carbon dioxide/Methane	0.67	1.36	20.8
1548	solvent-free [Ni3(μ3-OH)2(TBAPy)(H2O)4]· (DMF)x(dioxane)x	Carbon dioxide/Methane	1.34	2.14	19.5