Porous Molecular Crystals by Macrocyclic Coordination Supramolecules.

DOI: 10.1021/ja507555j

Jan. 1, 2014

Adsorbents

Ag(LSNf)]6(PF6)6  Ag(LSPhm-Me)]6(PF6)6 

Data points

#	Adsorbent	Gas	q / mol kg⁻¹	S / mol mol⁻¹	-ΔH / kJ mol⁻¹
1777	Ag(LSPhm-Me)]6(PF6)6	Carbon dioxide/Methane	0.27	2.0	25.5
1778	Ag(LSNf)]6(PF6)6	Carbon dioxide/Methane	0.22	2.5	25.0
3522	Ag(LSPhm-Me)]6(PF6)6	Carbon dioxide/Nitrogen	0.54	13.5	23.0
3523	Ag(LSNf)]6(PF6)6	Carbon dioxide/Nitrogen	0.45	13.3	25.0