Experimental and Theoretical Analysis of the Influence of Different Linker Molecules in Imidazolate Frameworks Potsdam (IFP-n) on the Separation of Olefin–Paraffin Mixtures

DOI: 10.1021/acs.langmuir.7b02016

Aug. 9, 2017

Adsorbents

Data points

# Adsorbent Gas q / mol kg⁻¹ S / mol mol⁻¹ -ΔH / kJ mol⁻¹
167 IFP-1 Ethane/Ethene 2.9 1.12 29.3
168 IFP-3 Ethane/Ethene 1.5 1.11 28.3
169 IFP-5 Ethane/Ethene 2.2 1.05 28.6
213 IFP-1 Propene/Propane 3.2 1.23 35.4
218 IFP-7 Propene/Propane 2.55 1.16 40.0
219 IFP-5 Propene/Propane 2.5 1.22 34.5
238 IFP-3 Propene/Propane 1.7 1.2 34.2