Structural Origin of Unusual CO2 Adsorption Behavior of a Small-Pore Aluminum Bisphosphonate MOF.

DOI: 10.1021/jp512596u

Jan. 1, 2015

Adsorbents

Data points

# Adsorbent Gas q / mol kg⁻¹ S / mol mol⁻¹ -ΔH / kJ mol⁻¹
1514 MIL-91(Al) Carbon dioxide/Methane 2.6 10.83 40.25
3238 MIL-91(Al) Carbon dioxide/Nitrogen 2.6 47.27 40.25
4923 MIL-91(Al) Methane/Nitrogen 0.23 4.6 25.0