A flexible zinc tetrazolate framework exhibiting breathing behaviour on xenon adsorption and selective adsorption of xenon over other noble gases.

DOI: 10.1039/C5TA00460H

Jan. 1, 2015

Adsorbents

Data points

# Adsorbent Gas q / mol kg⁻¹ S / mol mol⁻¹ -ΔH / kJ mol⁻¹
404 Zn(mtz)2 Argon/Nitrogen 0.15 1.5 11.9
412 Zn(mtz)2 Argon/Nitrogen 0.15 1.5 11.9
3826 Zn(mtz)2 Krypton/Argon 0.38 2.53 16.2
3827 Zn(mtz)2 Krypton/Argon 0.38 2.53 16.2
3841 Zn(mtz)2 Krypton/Nitrogen 0.38 3.8 16.2
3842 Zn(mtz)2 Krypton/Nitrogen 0.38 3.8 16.2
4286 Zn(mtz)2 Xenon/Argon 3.0 20.0 23.54
4287 Zn(mtz)2 Xenon/Argon 3.0 20.0 23.54
4329 Zn(mtz)2 Xenon/Krypton 3.0 7.89 23.54
4330 Zn(mtz)2 Xenon/Krypton 3.0 7.89 23.54
4354 Zn(mtz)2 Xenon/Nitrogen 3.0 30.0 23.54
4355 Zn(mtz)2 Xenon/Nitrogen 3.0 30.0 23.54