A Complex Self-Catenated Coordination Framework with a Rare (3,12)-Connected Underlying Net Showing Selective Adsorption of CO2.

DOI: 10.1002/ejic.201500715

Jan. 1, 2015

Adsorbents

CO2-NH2-BDC NH2-H2BDC

Data points

#	Adsorbent	Gas	q / mol kg⁻¹	S / mol mol⁻¹	-ΔH / kJ mol⁻¹
1445	CO2-NH2-BDC	Carbon dioxide/Methane	0.68	9.0	15.0
3138	CO2-NH2-BDC	Carbon dioxide/Nitrogen	0.68	15.3	15.0
4905	NH2-H2BDC	Methane/Nitrogen	0.08	1.7	None