Functionalized UiO-66 by Single and Binary (OH)2 and NO2 Groups for Uptake of CO2 and CH4.

DOI: 10.1021/acs.iecr.5b04061

Jan. 1, 2016

Adsorbents

Data points

# Adsorbent Gas q / mol kg⁻¹ S / mol mol⁻¹ -ΔH / kJ mol⁻¹
1509 UiO-66-(OH)2 Carbon dioxide/Methane 1.05 4.2 42.2
1510 UiO-66-(OH)2-NO2 Carbon dioxide/Methane 1.85 1.8 32.0
1511 UiO-66-NO2 Carbon dioxide/Methane 1.9 3.8 39.0
1512 UiO-66-NO2-(OH)2 Carbon dioxide/Methane 2.4 4.0 32.4