Four Simple Structure Carbazole-Based Conjugated Microporous Polymers with Different Soft Connected Chains.

DOI: 10.1002/macp.201500420

Jan. 1, 2016

Adsorbents

PCz–C3–Cz PCz–C4–Cz PCz–C5–Cz PCz–C6–Cz

Data points

#	Adsorbent	Gas	q / mol kg⁻¹	S / mol mol⁻¹	-ΔH / kJ mol⁻¹
1489	PCz–C3–Cz	Carbon dioxide/Methane	2.8	7.3	26.4
1490	PCz–C4–Cz	Carbon dioxide/Methane	2.54	6.7	23.65
1491	PCz–C5–Cz	Carbon dioxide/Methane	2.19	5.5	21.07
1492	PCz–C6–Cz	Carbon dioxide/Methane	2.24	5.8	26.82
3218	PCz–C3–Cz	Carbon dioxide/Nitrogen	2.8	33.8	26.4
3219	PCz–C4–Cz	Carbon dioxide/Nitrogen	2.54	18.6	23.65
3220	PCz–C5–Cz	Carbon dioxide/Nitrogen	2.19	17.4	21.07
3221	PCz–C6–Cz	Carbon dioxide/Nitrogen	2.24	24.3	26.82