High Ethene/Ethane Selectivity in 2,2′‐Bipyridine‐Based Silver(I) Complexes by Removal of Coordinated Solvent†

DOI: 10.1002/ange.201500251

March 12, 2015

Adsorbents

[AgI(2,2’-bipyridine)][BF4] [AgI(6,6’-dimethyl-2,2’-bipyridine)][OTf]

Data points

#	Adsorbent	Gas	q / mol kg⁻¹	S / mol mol⁻¹	-ΔH / kJ mol⁻¹
138	[AgI(2,2’-bipyridine)][BF4]	Ethene/Ethane	2.38	390.0	54.0
140	[AgI(6,6’-dimethyl-2,2’-bipyridine)][OTf]	Ethene/Ethane	2.18	340.0	55.0