Highly selective sorption of CO2 and N2O and strong gas-framework interactions in a nickel(II) organic material.
DOI: 10.1039/C6TA06572DJan. 1, 2016
Adsorbents
Data points
# | Adsorbent | Gas | q / mol kg⁻¹ | S / mol mol⁻¹ | -ΔH / kJ mol⁻¹ |
---|---|---|---|---|---|
1325 | Ni-MOF | Carbon dioxide/Methane | 3.34 | 33.0 | 32.0 |
3000 | Ni-MOF | Carbon dioxide/Nitrogen | 3.34 | 57.0 | 32.0 |
4014 | Ni-MOF | Nitrogen/Oxygen | 0.22 | 1.8 | None |
4858 | Ni-MOF | Methane/Nitrogen | 0.54 | 2.8 | 23.0 |