Porous Polyrotaxane Coordination Networks Containing Two Distinct Conformers of a Discontinuously Flexible Ligand.

DOI: 10.1021/acs.inorgchem.6b01713

Jan. 1, 2016

Adsorbents

Data points

# Adsorbent Gas q / mol kg⁻¹ S / mol mol⁻¹ -ΔH / kJ mol⁻¹
1324 Poly-[Zn2L2(bpe)0.5]2 Carbon dioxide/Methane 2.01 3.75 30.0
2999 Poly-[Zn2L2(bpe)0.5]2 Carbon dioxide/Nitrogen 2.9 26.0 27.0