Rational Synthesis and Investigation of Porous Metal-Organic Framework Materials from a Preorganized Heterometallic Carboxylate Building Block.

DOI: 10.1021/acs.inorgchem.6b02713

Jan. 1, 2017

Adsorbents

2-Br 2-H 2-NH2 2-NO2

Data points

#	Adsorbent	Gas	q / mol kg⁻¹	S / mol mol⁻¹	-ΔH / kJ mol⁻¹
1403	2-H	Carbon dioxide/Methane	1.34	3.7	None
1404	2-Br	Carbon dioxide/Methane	2.59	4.2	None
1405	2-NO2	Carbon dioxide/Methane	4.73	4.6	None
1406	2-NH2	Carbon dioxide/Methane	1.25	5.8	None