Overcoming Fundamental Limitations in Adsorbent Design: Alkene Adsorption by Non‐porous Copper(I) Complexes

DOI: 10.1002/anie.202010405

Aug. 25, 2020

Adsorbents

Data points

# Adsorbent Gas q / mol kg⁻¹ S / mol mol⁻¹ -ΔH / kJ mol⁻¹
132 [Cu-H]3 Ethene/Ethane 3.13 47.0 15.3
137 [Cu-Br]3 Ethene/Ethane 2.42 46.5 9.6
349 [Cu-H]3 Propene/Propane 2.8 29.0 None
354 [Cu-Br]3 Propene/Propane 2.09 39.5 17.0
359 [Cu-Br]3 Propene/Propane 1.49 27.0 None
364 [Cu-H]3 Propene/Propane 0.1 40.0 None