A porous the-type metal-organic framework based on [Mn4Cl]7+ clusters for selective gas sorption.
DOI: 10.1016/j.inoche.2017.03.021Jan. 1, 2017
Adsorbents
Data points
| # | Adsorbent | Gas | q / mol kg⁻¹ | S / mol mol⁻¹ | -ΔH / kJ mol⁻¹ |
|---|---|---|---|---|---|
| 593 | {(Me2NH2)5[Mn4Cl(BTB)4(H2O)4](DMF)2(EtOH)7}n | Methane/Nitrogen | 1.03 | 4.62 | None |
| 1352 | {(Me2NH2)5[Mn4Cl(BTB)4(H2O)4](DMF)2(EtOH)7}n | Carbon dioxide/Methane | 2.25 | 4.7 | 23.2 |
| 3032 | {(Me2NH2)5[Mn4Cl(BTB)4(H2O)4](DMF)2(EtOH)7}n | Carbon dioxide/Nitrogen | 3.88 | 17.4 | 23.2 |