Improving Gas Separation Performance of ZIF-8 by [BMIM][BF4] Incorporation: Interactions and Their Consequences on Performance.

DOI: 10.1021/acs.jpcc.7b00848

Jan. 1, 2017

Adsorbents

Data points

# Adsorbent Gas q / mol kg⁻¹ S / mol mol⁻¹ -ΔH / kJ mol⁻¹
1383 ZIF-8 Carbon dioxide/Methane 0.47 2.5 18.4
1384 IL4/ZIF-8 Carbon dioxide/Methane 0.47 1.02 18.35
1385 IL20/ZIF-8 Carbon dioxide/Methane 0.46 1.18 21.0
1386 IL28/ZIF-8 Carbon dioxide/Methane 0.45 1.42 29.0
3062 ZIF-8 Carbon dioxide/Nitrogen 0.47 7.4 18.4
3063 IL4/ZIF-8 Carbon dioxide/Nitrogen 0.47 1.06 18.35
3064 IL20/ZIF-8 Carbon dioxide/Nitrogen 0.46 1.06 21.0
3065 IL28/ZIF-8 Carbon dioxide/Nitrogen 0.45 1.58 29.0
4878 ZIF-8 Methane/Nitrogen 0.31 3.5 13.0
4879 ZIF-8/IL4 Methane/Nitrogen 0.33 5.38 14.0
4880 ZIF-8/IL20 Methane/Nitrogen 0.31 2.75 14.0
4881 ZIF-8/IL28 Methane/Nitrogen 0.25 4.0 20.0