Boronic Acid Moiety as Functional Defect in UiO-66 and Its Effect on Hydrogen Uptake Capacity and Selective CO2 Adsorption: A Comparative Study.

DOI: 10.1021/acsami.7b16937

Jan. 1, 2018

Adsorbents

UiO-66 UiO-66-1 UiO-66-2 UiO-66B 0.5/0.5 UiO-66B 0.62/0.38 UiO-66B 0.75/0.25 UiO-66B 0.87/0.13

Data points

#	Adsorbent	Gas	q / mol kg⁻¹	S / mol mol⁻¹	-ΔH / kJ mol⁻¹
1215	UiO-66-1	Carbon dioxide/Methane	1.7	14.1	None
2776	UiO-66-1	Carbon dioxide/Nitrogen	1.7	74.9	None
2777	UiO-66-2	Carbon dioxide/Nitrogen	1.7	19.4	None
2778	UiO-66-2	Carbon dioxide/Nitrogen	1.7	6.3	None
4808	UiO-66	Methane/Nitrogen	0.35	2.92	None
4809	UiO-66B 0.87/0.13	Methane/Nitrogen	0.4	3.33	None
4810	UiO-66B 0.75/0.25	Methane/Nitrogen	0.35	2.92	None
4811	UiO-66B 0.62/0.38	Methane/Nitrogen	0.3	2.5	None
4812	UiO-66B 0.5/0.5	Methane/Nitrogen	0.12	6.0	None