In Situ 13C NMR Spectroscopy Study of CO2/CH4 Mixture Adsorption by Metal-Organic Frameworks: Does Flexibility Influence Selectivity?.

DOI: 10.1021/acs.langmuir.8b03554

Jan. 1, 2019

Adsorbents

DUT-8 (Ni) flex DUT-8 (Ni) rigid SNU-9

Data points

#	Adsorbent	Gas	q / mol kg⁻¹	S / mol mol⁻¹	-ΔH / kJ mol⁻¹
1009	SNU-9	Carbon dioxide/Methane	0.91	8.27	None
1010	DUT-8 (Ni) rigid	Carbon dioxide/Methane	1.8	180.0	None
1011	DUT-8 (Ni) flex	Carbon dioxide/Methane	0.22	1000.0	None