Immobilization of Ag(I) into a metal–organic framework with –SO3H sites for highly selective olefin–paraffin separation at room temperature
DOI: 10.1039/C4CC09679GJan. 12, 2015
Adsorbents
Data points
| # | Adsorbent | Gas | q / mol kg⁻¹ | S / mol mol⁻¹ | -ΔH / kJ mol⁻¹ |
|---|---|---|---|---|---|
| 68 | (Cr)-MIL-101-SO3Ag | Ethene/Ethane | 2.61 | 16.0 | 120.0 |
| 85 | (Cr)-MIL-101-SO3H | Ethene/Ethane | 1.7 | 1.2 | 35.0 |
| 291 | (Cr)-MIL-101-SO3H | Propene/Propane | 4.54 | 1.83 | 41.0 |
| 293 | (Cr)-MIL-101-SO3Ag | Propene/Propane | 4.32 | 32.0 | 101.0 |