Highly selective adsorption of ethylene over ethane in a MOF featuring the combination of open metal site and π-complexation

DOI: 10.1039/C4CC09774B

Jan. 9, 2015

Adsorbents

Data points

# Adsorbent Gas q / mol kg⁻¹ S / mol mol⁻¹ -ΔH / kJ mol⁻¹
66 MIL-101–Cr–SO3Ag Ethene/Ethane 2.81 9.7 63.0
89 MIL-101–Cr–SO3H Ethene/Ethane 1.65 1.2 10.0