Highly selective adsorption of ethylene over ethane in a MOF featuring the combination of open metal site and π-complexation
DOI: 10.1039/C4CC09774BJan. 9, 2015
Adsorbents
Data points
# | Adsorbent | Gas | q / mol kg⁻¹ | S / mol mol⁻¹ | -ΔH / kJ mol⁻¹ |
---|---|---|---|---|---|
66 | MIL-101–Cr–SO3Ag | Ethene/Ethane | 2.81 | 9.7 | 63.0 |
89 | MIL-101–Cr–SO3H | Ethene/Ethane | 1.65 | 1.2 | 10.0 |