Flexible bifunctional monoethylphosphonate/carboxylates of Zn(II) and Co(II) reinforced with DABCO co-ligand: paradigmatic structural organization with pcu topology.

DOI: 10.1039/d0ce00275e

Jan. 1, 2020

Adsorbents

[Co2(EtBCP)2(DABCO)0.5] [ZN2(EtBCP)2(DABCO)0.5]

Data points

#	Adsorbent	Gas	q / mol kg⁻¹	S / mol mol⁻¹	-ΔH / kJ mol⁻¹
989	[ZN2(EtBCP)2(DABCO)0.5]	Carbon dioxide/Methane	0.9	4.09	33.0
990	[Co2(EtBCP)2(DABCO)0.5]	Carbon dioxide/Methane	1.0	3.45	21.0