High propene/propane selectivity in isostructural metal–organic frameworks with high densities of open metal sites
DOI: 10.1002/anie.201107534Jan. 16, 2012
Adsorbents
Data points
| # | Adsorbent | Gas | q / mol kg⁻¹ | S / mol mol⁻¹ | -ΔH / kJ mol⁻¹ |
|---|---|---|---|---|---|
| 41 | Co-MOF-74 | Ethene/Ethane | 6.9 | 8.4 | None |
| 277 | Co-MOF-74 | Propene/Propane | 7.29 | 46.0 | 49.0 |
| 286 | Mn-MOF-74 | Propene/Propane | 6.0 | 24.0 | 45.1 |
| 287 | Mg-MOF-74 | Propene/Propane | 5.9 | 4.5 | 44.8 |