Structural Dynamism-Actuated Reversible CO2 Adsorption Switch and Postmetalation-Induced Visible Light Cα-H Photocyanation with Rare Size Selectivity in N-Functionalized 3D Covalent Organic Framework.
DOI: 10.1021/acsami.0c14678Jan. 1, 2020
Adsorbents
Data points
| # | Adsorbent | Gas | q / mol kg⁻¹ | S / mol mol⁻¹ | -ΔH / kJ mol⁻¹ |
|---|---|---|---|---|---|
| 800 | Activated COF | Carbon dioxide/Methane | 3.7 | 6.0 | 34.0 |
| 2376 | Activated COF | Carbon dioxide/Nitrogen | 3.7 | 32.0 | 34.0 |
| 4675 | COF | Methane/Nitrogen | 0.89 | 6.67 | None |