Sorption of N2, O2, and Ar in Mn(II)-Exchanged Zeolites A and X Using Volumetric Measurements and Grand Canonical Monte Carlo Simulation.

DOI: 10.1021/ie070067w

Jan. 1, 2007

Adsorbents

MnA 41 MnA 59 MnA 74 MnA 89 MnA 99 MnX 100 MnX 47 MnX 60 MnX 71 MnX 79 MnX 90 NaA NaX

Data points

#	Adsorbent	Gas	q / mol kg⁻¹	S / mol mol⁻¹	-ΔH / kJ mol⁻¹
3893	NaA	Nitrogen/Argon	0.34	3.4	21.3
3894	MnA 41	Nitrogen/Argon	0.41	3.42	22.2
3895	MnA 59	Nitrogen/Argon	0.43	3.58	24.1
3896	MnA 74	Nitrogen/Argon	0.46	3.54	25.6
3897	MnA 89	Nitrogen/Argon	0.47	3.62	26.5
3898	MnA 99	Nitrogen/Argon	0.47	3.62	28.4
3899	NaX	Nitrogen/Argon	0.41	3.42	21.5
3900	MnX 47	Nitrogen/Argon	0.34	3.78	29.2
3901	MnX 60	Nitrogen/Argon	0.35	3.89	32.6
3902	MnX 71	Nitrogen/Argon	0.35	3.89	35.2
3903	MnX 79	Nitrogen/Argon	0.42	4.67	37.3
3904	MnX 90	Nitrogen/Argon	0.35	3.89	40.0
3905	MnX 100	Nitrogen/Argon	0.36	4.0	40.2
4036	NaA	Nitrogen/Oxygen	0.34	3.09	21.3
4037	MnA 41	Nitrogen/Oxygen	0.41	2.93	22.2
4038	MnA 59	Nitrogen/Oxygen	0.43	2.87	24.1
4039	MnA 74	Nitrogen/Oxygen	0.46	2.88	25.6
4040	MnA 89	Nitrogen/Oxygen	0.47	2.76	26.5
4041	MnA 99	Nitrogen/Oxygen	0.47	2.76	28.4
4042	NaX	Nitrogen/Oxygen	0.41	3.15	21.5
4043	MnX 47	Nitrogen/Oxygen	0.34	2.83	29.2
4044	MnX 60	Nitrogen/Oxygen	0.35	2.92	32.6
4045	MnX 71	Nitrogen/Oxygen	0.35	2.92	35.2
4046	MnX 79	Nitrogen/Oxygen	0.42	3.5	37.3
4047	MnX 90	Nitrogen/Oxygen	0.35	2.92	40.0
4048	MnX 100	Nitrogen/Oxygen	0.36	3.0	40.2
4172	NaA	Oxygen/Argon	0.11	1.1	15.3
4173	MnA 41	Oxygen/Argon	0.14	1.17	15.1
4174	MnA 59	Oxygen/Argon	0.15	1.25	15.2
4175	MnA 74	Oxygen/Argon	0.16	1.23	15.3
4176	MnA 89	Oxygen/Argon	0.17	1.31	15.4
4177	MnA 99	Oxygen/Argon	0.17	1.31	15.4
4178	NaX	Oxygen/Argon	0.13	1.08	15.1
4179	MnX 47	Oxygen/Argon	0.12	1.33	15.8
4180	MnX 60	Oxygen/Argon	0.12	1.33	16.2
4181	MnX 71	Oxygen/Argon	0.12	1.33	16.4
4182	MnX 79	Oxygen/Argon	0.12	1.33	16.6
4183	MnX 90	Oxygen/Argon	0.12	1.33	16.7
4184	MnX 100	Oxygen/Argon	0.12	1.33	17.2